How to Handle Hazardous Materials Safely & Prevent Warehouse Incidents

Posted by Sebastian Gomez, CEP on January 27, 2021
( Last updated on 31 July, 2021)
Sebastian Gomez, CEP

Many warehouses across North America contain or store to some degree, hazardous materials. From gas cylinders to liquid paint, warehouse facilities are the most common sites where hazmat incidents occur. According to The United States Agency for Toxic Substances and Disease Registry (ATSDT), 75% of hazmat emergencies occur in storage facilities. Of these incidents, 36% involve the storage of incompatible chemicals and 22% occur while using the wrong storage equipment. Having accidents within a storage facility that has hazardous materials can be dangerous for all warehouse occupants. Hazards can cause short to long-term effects. There are two different types of hazards: physical and health-related (Figure 1). Safety precautions and procedures exist to limit the occurrence of such accidents, such as the installation of labels, frequent inspections of goods, effective storage, and other useful safety measures. In this article, we will cover theExplosives different methods of safeguarding warehouse personnel from potential hazards and the preventative measures that can be implemented throughout the warehouse to encourage a safer workplace.

PHYSICAL
Materials that present effects like:
HEALTH
Some of the health hazard classifications are:
Fire

Corrosion

Reaction with other materials
Acute toxicity

Skin irritation

Respiratory distress

Eye Damage

Long-term carcinogen effects
Figure 1. Different types of hazards.

Why Labelling Unsafe Substances Is Important

Labels are the easiest way to spot what kind of hazards you could be facing. Having the correct labels will not only help in the identification of different substances that come into the warehouse but will also help when it comes to separating and organizing them. The table below shows the main labels used to identify hazardous materials across North America:

CATEGORY USA CANADA
Explosives
Gases
Flammable & Combustible Liquids
Flammable Solids
Oxidizing Substances & Organic Peroxides
Toxic Infectious Substances
Radioactive Materials
Corrosives
Miscellaneous Dangerous Goods
Biohazardous Infectious Materials
Health Hazard
Environment (May cause damage to aquatic environment.)
Exclamation Mark (May have less serious health effect or damage the ozone)

There are a lot of similarities between the Canadian and American labels. Although one key difference is the color coding. As shown in the table above, the labels for the U.S. have different colors. This helps differentiate between the types of hazard that certain materials can have. The “Hazard Diamond” from the National Fire Protection Association (NFPA 704) shown in Figure 2 conveys health warning information for emergency response teams.

Uline Diamond
Figure 2. Hazard Diamond (Uline)

With the help of labels, it is a lot easier to separate these hazardous substances. It is also important to keep incompatible materials at a distance from each other such as:

  • Acid + Bases
  • Flammables + Oxidizers
  • Water Reactive + Aqueous Solutions

rack-damage-assessment-poster

Special Storage for Dangerous Warehouse Materials

Having an organized warehouse with labelled products and sectioned off areas helps facilitate the storing process for hazardous substances. In addition, there are key procedures which can help improve warehouse safety when it comes to hazardous materials. They are as follows:

  • Have an organized receiving area with information and paperwork for every substance that is received to properly identity what comes in and goes out.
  • Every individual material that is received should be accompanied by a Material Safety Data Sheet (MSDS) which provides:
    • Product information
    • Hazardous ingredients
    • Physical data
    • Fire and explosion hazard data
    • Reactivity data
    • Toxicological properties
    • Preventive measures
    • First aid measures
    • Preparation information
  • Check for damages when goods are received (holes, leaks, or any other damages that can increase risks of spills).
  • It is important when storing hazardous substances to keep areas properly ventilated and keep them far away from heat sources and direct sunlight.
  • Use chemical resistant structure materials within the facility.
  • Use chemically approved containers, cabinets, and refrigerating units.
  • Store the incoming materials based on chemical compatibility and not alphabetically.
  • Make sure the ventilation (supply and exhaust systems), follows the ASHRAE Standards 62.1 and 62.2 for hazardous materials.
  • Make sure the sprinkler system (whether it is a foam or water), complies with the NFPA Chapter 16 and 17 for hazardous materials.
  • When storing products in pallet racks, make sure you have updated LARCs (Load Application and Rack Configuration drawings). To learn more about why LARCs are so important, read this article. Regularly inspect the racks for damages, non-conforming issues to the rack design code or discrepancy with LARCs (the original engineer-approved drawings).
Chemical storage cabinets
Figure 3. Chemical storage cabinets (Barrier Holden, 2014)
Receipt of good area
Figure 4. Receipt of goods area (Health and Safety Executive, 2009)

Moving and Stacking Hazardous Materials on Pallets

When handling and moving hazardous materials on pallets and storing them on pallet racks, there are several factors to consider. Some of the treated wood pallets are very toxic and are not safe to use for storing hazardous material. To ensure that you are using the right pallet with a safety pallet treatment, always look for the pallet stamp. For additional information on the different types of pallets available in the industry, read this article.

Example of Pallet Stamp
Figure 5. Sample Pallet Stamp (Lovely Greens, 2013)
Treatment Codes on Pallet Stamps
Figure 6. Types of treatment codes on pallet stamps (Eric Brennan, 2014)

Not only do the pallets you use matter when storing hazardous material, but also the way you stack the material. There are two main configurations to properly stack and secure the substances on the pallets:

  • Interlinked stacking
  • Strapping

Interlinked Stacking

The stability of the packaging stock on the pallet can be increased significantly by the stacking method. Intermediate layers, e.g. made of laminated paper or corrugated cardboard, represent a layer bond with the drums. With the interlinked stacking of boxes, the unburdened upper layer often must be held together. If the individual pieces (e.g. boxes) are very light, the layers should also be secured with shrink wrap.

Interlinked stacking
Figure 7. Interlinked stacking for boxes and cylinders (Berufgenossenschaft Rohstoffe und chmische Industrie, 2013)

Strapping

Packaging on a pallet can be made more stable with the aid of vertical and/or horizontal strapping using textile, plastic, or steel lashing straps. With boxes made of corrugated cardboard, conical packaging or soft packaging, attention must be paid to the tightness of the strap as this can damage the packaging. To help avoid this, edge protectors are used to spread the clamping force of the straps.

Interlinked stacking-1
Figure 8. Strapping for Boxes and Cylinders (Berufgenossenschaft Rohstoffe und chmische Industrie, 2013)
Example of strapping and interlinked stacking
Figure 9. Examples of strapping and interlinked stacking (Health and Safety Executive, 2009)

Hazardous Material Spill Prevention and Response

According to the Workplace Hazardous Materials Information System (WHMIS), there is always a chance that a spill or leak can happen when chemicals are used in the workplace. The key is to be prepared with an efficient clean-up plan. Having the necessary tools and equipment can go a long way to avoid spills from affecting the health and lives of workers.

Below are three proactive steps you can take to be better prepared for a potential spill:

  1. Purchase proper employee attire for safe handling of hazardous materials: Personal protective equipment (PPE) is vital for keeping your employees safe when handling hazardous materials. At the minimum, workers must have eye protection, gloves, and boots. Most warehouse situations rarely require full hazmat suits, but proper coveralls are strongly recommended. Face shields are also recommended when handling corrosive materials.
  2. Post signs and visual aids: Carry a full assortment of visual aids like preventative floor signs, floor safety tape, tool shadow tape, and aisle markings.
  3. Install spill pallets: Installing spill pallets (Figure 10) beneath the liquid storage containers to prevent danger of leaks and spills. The size of the container will determine the size of the pallet. Drums containing 55 gallons or more must have a full coverage spill pallet to be able to catch spills on all sides. The spill pallet must be designed to hold at least 35% of the drums content.
Spill pallets
Figure 10. Spill pallets (ENPAC Spill Pallets)

Beyond these preventative measures, there are also best practices that should be followed in response to a spill. These include not touching the spilled material, containing it with an absorbent material, assessing how the spill occurred in the first place, and finally, planning how to prevent it from happening again. More comprehensive lists of how to properly respond to a spill can be found on the United States Department of Labor website and on the Government of Canada website.

Traffic Routes: The Safe Transportation of Hazardous Materials Throughout the Warehouse

Although there is no official guideline for traffic routes when warehousing hazardous material in North America, having ample amount of space to maneuver pallets with lifts can reduce the impact on accidental damages that can result in leaks and spills. Within the Health and Safety Executive (HSE) in the United Kingdom, traffic routes in warehouses for hazardous substances must have a specific width. In the case of traffic routes for workers, these must be at least 2.5ft (0.75m) wide, and for forklift traffic the routes must have the width of the forklift plus at least 1.64ft (0.5m) on each side of the fork-lift truck.

Traffic routes for lifts and workers
Figure 11. Traffic routes for lifts and workers (Berufgenossenschaft Rohstoffe und chmische Industrie, 2013)

Takeaway on Hazardous Materials Safety

Looking at each point presented, they all play a key role in protecting not only the materials being stored but the employees from potential physical and health hazards. It is important to take these into consideration when operating a warehouse that stores hazardous material and take the necessary precautions such as:

  • Properly reading the MSDS documentation when goods arrive
  • Organizing the material and properly storing it
  • Frequently inspecting the hazardous material for damages or any observable issues
  • Supply warehouse workers with proper PPE and training to handle the material in case of a spill

For more information regarding these topics, you can refer to the most recent versions of the Codes and Standards below:

It is equally important to integrate good rack safety procedures that will help protect the hazardous materials from being damaged. Respecting North American rack design codes and conducting regular rack inspections considerably reduces the risk of rack collapse. Find a reliable and experienced rack safety partner who can guide you in finding the most suitable and efficient rack safety solutions to not only safely store your hazardous materials, but to also help you improve the overall safety of your warehouse.

References:

Aldrich, S. (2011, February 8). MSDS sheet for Chromium Acetate Hydroxide. Retrieved from sigmaaldrich.com:
Barrier Holden. (2014, September 11). Safety Storage Center. Retrieved from safetystoragecenter.co.uk: https://www.safetystoragecentre.co.uk/articles/dont-get-fingers-burned-use-store-chemicals-safely/

Berufgenossenschaft Rohstoffe und chmische Industrie. (2013, November ). Storage of Hazardous Substances. Retrieved from ASECOS: https://www.asecos.com/dokumente/M062_Code-of-Practice_Storage-of-Hazardous-Substances.pdf

Dull, J. (2019, June 18). OSHA Floor Markings. Retrieved from ifloortape.com: https://ifloortape.com/osha-floor-marking-safety-5s-nsc/
 
Eric Brennan. (2014, October 6). Preparing Wooden Pallets for Upcycling Projects. Retrieved from fix.com: https://www.fix.com/blog/preparing-wood-pallets-for-upcycling/

Health and Safety Executive. (2009). Chemical Warehousing: The storage of packaged dangerous substances. Retrieved from Safety Resources Blog: https://safetyresourcesblog.files.wordpress.com/2014/10/chemical-warehousing.pdf
 
Lovely Greens. (2013, May 6). How to Make a Better Strawberry Pallet Planter. Retrieved from lovelygreens.com: https://lovelygreens.com/how-to-make-better-strawberry-pallet/
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